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Radiocarbon (¹⁴C) is a critical tool for understanding the global carbon cycle. During the Anthropocene, two new processes influenced¹⁴C in atmospheric, land and ocean carbon reservoirs. First,¹⁴C-free carbon derived from fossil fuel burning has diluted¹⁴C, at rates that have accelerated with time. Second, ‘bomb’¹⁴C produced by atmospheric nuclear weapon tests in the mid-twentieth century provided a global isotope tracer that is used to constrain rates of air–sea gas exchange, carbon turnover, large-scale atmospheric and ocean transport, and other key C cycle processes. As we write, the¹⁴C/¹²C ratio of atmospheric CO₂is dropping below pre-industrial levels, and the rate of decline in the future will depend on global fossil fuel use and net exchange of bomb¹⁴C between the atmosphere, ocean and land. This milestone coincides with a rapid increase in¹⁴C measurement capacity worldwide. Leveraging future¹⁴C measurements to understand processes and test models requires coordinated international effort—a ‘decade of radiocarbon’ with multiple goals: (i) filling observational gaps using archives, (ii) building and sustaining observation networks to increase measurement density across carbon reservoirs, (iii) developing databases, synthesis and modelling tools and (iv) establishing metrics for identifying and verifying changes in carbon sources and sinks.

This article is part of the Theo Murphy meeting issue 'Radiocarbon in the Anthropocene'.

 

Abstract. Sometime during the middle to late Holocene (8.2 ka to ∼ 1850–1900 CE), the Greenland Ice Sheet (GrIS) was smaller than its currentconfiguration. Determining the exact dimensions of the Holocene ice-sheetminimum and the duration that the ice margin rested inboard of its currentposition remains challenging. Contemporary retreat of the GrIS from itshistorical maximum extent in southwestern Greenland is exposing a landscapethat holds clues regarding the configuration and timing of past ice-sheetminima. To quantify the duration of the time the GrIS margin was near itsmodern extent we develop a new technique for Greenland that utilizes in situcosmogenic 10Be–14C–26Al in bedrock samples that have becomeice-free only in the last few decades due to the retreating ice-sheet margin atKangiata Nunaata Sermia (n=12 sites, 36 measurements; KNS), southwest Greenland. To maximizethe utility of this approach, we refine the deglaciation history of the regionwith stand-alone 10Be measurements (n=49) and traditional 14C agesfrom sedimentary deposits contained in proglacial–threshold lakes. We combineour reconstructed ice-margin history in the KNS region with additionalgeologic records from southwestern Greenland and recent model simulations ofGrIS change to constrain the timing of the GrIS minimum in southwestGreenland and the magnitude of Holocene inland GrIS retreat, as well as to explore theregional climate history influencing Holocene ice-sheet behavior. Our10Be–14C–26Al measurements reveal that (1) KNS retreated behindits modern margin just before 10 ka, but it likely stabilized near thepresent GrIS margin for several thousand years before retreating fartherinland, and (2) pre-Holocene 10Be detected in several of our sample sitesis most easily explained by several thousand years of surface exposure duringthe last interglaciation. Moreover, our new results indicate that the minimumextent of the GrIS likely occurred after ∼5 ka, and the GrISmargin may have approached its eventual historical maximum extent as early as∼2 ka. Recent simulations of GrIS change are able to match thegeologic record of ice-sheet change in regions dominated by surface massbalance, but they produce a poorer model–data fit in areas influenced by oceanicand dynamic processes. Simulations that achieve the best model–data fitsuggest that inland retreat of the ice margin driven by early to middleHolocene warmth may have been mitigated by increased precipitation. Triple10Be–14C–26Al measurements in recently deglaciated bedrockprovide a new tool to help decipher the duration of smaller-than-present iceover multiple timescales. Modern retreat of the GrIS margin in southwestGreenland is revealing a bedrock landscape that was also exposed during themigration of the GrIS margin towards its Holocene minimum extent, but it has yetto tap into a landscape that remained ice-covered throughout the entireHolocene. 

ABSTRACT Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.